Periodic Table of the Elements
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Bottom FACULTY OF CHEMICAL TECHNOLOGY o PERIODIC TABLE OF THE ELEMENTS Bottom
  A B C D E F G H I J K L M N O P R S T U V X Z  
Periodic Table of the Elements Tableau périodique des éléments Periodni sustav elemenata Tavola periodica degli elementi Das Periodensystem der Elemente
Molybdenum Molybdène Molibden Molibdeno Molybdän

 
Atomic number: 42
Group numbers: 6
Period: 5
 
Discovery date: 1778
Mo

Molybdenum

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Molybdenum was discovered by Carl William Scheele (Sweden) in 1778. The origin of the name comes from the Greek word molybdos meaning lead. It is silvery white, very hard metal, but is softer and more ductile than tungsten.
Bottom TRANSITION ELEMENT: CHROMIUM GROUP Top

Relative atomic mass: 95.94(1) Electronic configuration: [Kr] 4d5 5s1
Formal oxidation number: +6 Electronegativities: 2.16
Thermal conductivity: 138 W m-1 K-1 Electrical resistivity (20 °C): 5.34 μΩcm
Atomic radius: 136.3 pm Standard state (20 °C): solid
Density (g dm-3): 10220 (293 K)
9330 (m.p.)
Molar volume (cm3 mol-1): 9.39 (293 K)
10.28 (m.p.)


Bottom THERMAL PROPERTIES Top

Melting point: 2623 °C Heat of fusion: 27.6 kJ mol-1
Boiling point: 4639 °C Heat of vaporization: 589.9 kJ mol-1
Critical temperature: 9177 °C Heat of atomization: 656.55 kJ mol-1


Bottom IONIZATION ENERGIES AND ABUNDANCE Top

1st ionization energy: 684.32 kJ mol-1 Abundance of element (air): - ppm
2nd ionization energy: 1559.21 kJ mol-1 Abundance of element (Earth's crust): 1 ppm
3rd ionization energy: 2617.67 kJ mol-1 Abundance of element (oceans): 0.01 ppm


Bottom ISOTOPES Top

Isotopes Relative atomic mass Abundance (%)
92Mo91.906810(4)14.84(4)
94Mo93.905088(2)9.25(3)
95Mo94.905841(2)15.92(5)
96Mo95.904679(2)16.68(5)
97Mo96.906021(2)9.55(3)
98Mo97.905408(2)24.13(7)
100Mo99.907477(6)9.63(3)


Bottom MINERALS AND USES Top

Molybdenum is found in the minerals molybdenite (MoS2) and wulfenite (MoO4Pb). Its alloys are used in aircraft, missiles and protective coatings in boiler plate. The price of 99.7 % pure molybdenum pellets is 96.90 € for 500 g.

Bottom REDUCTION POTENTIALS Top

Balanced half-reaction   Eo / V      Annotation
MoVI + e- = MoV +0.43  4.6 mol dm-3 H2SO4
MoIII + 3e- = Mo(s) - 0.2  
H2MoO4(aq) + 2H+ + e- = MoO2+ + 2H2O +0.4  
HMoO4- + 3H+ + 2e- = MoO2 + 2H2O +0.429  
MoO42- + 4H+ + 2e- = MoO2 + 2H2O +0.606  
HMoO4- + 7H+ + 3e- = Mo3+ + 4H2O +0.390  
MoO42- + 8H+ + 3e- = Mo3+ + 4H2O +0.508  
MoO42- + 8H+ + 6e- = Mo(s) + 4H2O +0.154  
MoO42- + 4H2O + 6e- = Mo(s) + 8OH- - 1.05  

 

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Last modified: 01.04.2003
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